The specials focus on an original protagonist and former assistant of Professor Sycamore, Alain, and his partner, a Mega Charizard X, and his quest to research and defeat every known Mega-Evolved Pokémon. He is joined by Mairin, a beginning Trainer who started with her Chespin, nicknamed Chespie. Other characters include Steven, the Hoenn League Champion, and Lysandre, a mysterious benefactor who has his own reasons for pursuing Mega Evolution.

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